FIELD: technological processes.
SUBSTANCE: invention relates to a method for processing red mud while preparation of scandium-containing concentrate and scandium oxide in which carbonization leaching is conducted, sorption of scandium on phosphorus-containing ionite, desorption of scandium and precipitation of scandium concentrate. Content of Sc2O3 is not less than 15 % by weight (in dry basis), TiO2 not more than 3 % by weight (in dry basis), ZrO2 not more than 15 % by weight (in dry basis), and scandium in the concentrate is in the form of a mixture of hydroxide Sc(OH)3 with a basic salt of ScOHCO3×4H2O. Preparation of high purity scandium oxide from said concentrate includes dissolving scandium-containing concentrate in sulfuric acid.
EFFECT: technical result is increased extraction rate of scandium from red mud and increased purity of the products obtained.
14 cl, 1 dwg, 8 tbl, 4 ex
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Authors
Dates
2018-03-15—Published
2016-08-04—Filed