FIELD: chemistry.
SUBSTANCE: invention relates to the method of producing polyquinone and ethylene bisphenol of the general formula , which is an effective antioxidant for synthetic rubbers, polyolefins, and lubricants. The method includes oxidizing monomers: hydroquinone and/or benzoquinone, and/or quinhydron, and/or pyrocatechol, with a dehydrogenating agent, which is a spatially substituted stilbenquinone of the general formula ; and the process is carried out at a temperature of 100-200°C, in the presence of water in a neutral medium, or an acid medium, or an alkaline medium mixed with a hydrocarbon solvent in which the dehydrogenating agent and the starting monomer are dissolved, where R1-4 is tert-butyl.
EFFECT: method allows to obtain polyquinone with a high yield with a high conversion of spatially substituted stilbenquinone and using a simplified technology.
2 cl, 1 tbl, 14 ex
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Authors
Dates
2018-03-16—Published
2015-12-23—Filed