FIELD: metallurgy.
SUBSTANCE: invention relates to recovery of rare earth metals from raw materials containing these elements. Selective extraction is carried out from saturated mother liquors in the form of oxalates of REE. Bittern is contacted with oxalic acid, followed by aging to precipitate the metal oxalates. Oxalates are separated from the depleted REE solution. Resulting solutions of rare-earth elements have extremely high purity and can be pretreated directly in the solvent extraction cycle for separation of rare-earth elements or can be post-processed for the direct production of 99.9 % of the bulk concentrate of hydroxides/oxides of rare-earth elements.
EFFECT: high purity of extracted rare-earth elements.
23 cl, 12 dwg, 5 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PHOSPHITE PROCESSING | 2014 |
|
RU2552602C2 |
METHOD FOR PHOSPHOGYPSUM PROCESSING | 2017 |
|
RU2665512C1 |
METHOD OF COMPLEX PROCESSING PHOSPHOGYPSUM | 2017 |
|
RU2639394C1 |
METHOD FOR PRODUCING HIGH-PURE HYDRATED NICKEL SULFATE | 2019 |
|
RU2797855C2 |
METHOD OF PHOTOMETRIC DETERMINATION OF RARE EARTH ELEMENTS | 2012 |
|
RU2511375C2 |
PHOSPHOSEMIHYDRATE PROCESSING METHOD | 2012 |
|
RU2507276C1 |
METHOD OF PROCESSING MONAZITE CONCENTRATE | 2013 |
|
RU2549412C1 |
METHOD OF PROVIDING ENVIRONMENTAL SAFETY OF PRODUCTION WASTE AS PHOSPHOGYPSUM WITH PRODUCTION OF TWO-COMPONENT TARGET PRODUCT | 2016 |
|
RU2630072C2 |
METHOD OF PROCESSING PHOSPHOGYPSUM | 2014 |
|
RU2551292C2 |
METHOD OF PROCESSING PHOSPHOGYPSUM | 2015 |
|
RU2610186C1 |
Authors
Dates
2018-04-20—Published
2014-01-18—Filed