CATALYST FOR PRODUCING BIO-BASED ACRYLIC ACID AND ITS DERIVATIVES AND THE METHOD FOR MAKING THEREOF Russian patent published in 2018 - IPC B01J37/04 B01J27/18 B01J37/08 B01J37/10 C07C57/04 C07C51/377 C07C57/55 

Abstract RU 2662229 C2

FIELD: chemistry.

SUBSTANCE: present invention relates to a catalyst for the production of acrylic acid based on a biological feed comprising phosphate anions and at least one monovalent cation and at least one multivalent cation. Process for the preparation of a catalyst is also provided. Lactic acid, lactic acid derivatives or mixtures thereof are dehydrated by a catalyst in a process for the production of acrylic acid, acrylic acid derivatives or mixtures thereof based on biological raw materials. In particular, the invention relates to a catalyst for the conversion of lactic acid, lactic acid derivatives or mixtures thereof to acrylic acid, acrylic acid derivatives or mixtures thereof comprising (a) phosphate anions described by formulas (Ic) and (IIc), (b) to at least two different cations, wherein the catalyst is neutrally charged, and β and γ greater than or equal to 0 and less than or equal to 1, wherein n is at least 2, wherein the molar ratio of said phosphate anions in said catalyst is from about 0.1 to about 10, said at least two different cation include at least one monovalent cation and at least one multivalent cation, and wherein said multivalent cation is selected from the group consisting of metal cations Be, Mg, Ca, Sr, Ba and their mixtures. [H(2-2γ)PO(4-γ)](1+(n-1)γ)-(1+(n-1)γ) (IIc), and [H(1-β)P(1+β)O(4+3β)]2(1+β)- (Ic).

EFFECT: catalyst allows to obtain products with high yield, selectivity and efficiency.

14 cl, 7 ex

Similar patents RU2662229C2

Title Year Author Number
METHOD OF PRODUCTION OF ACRYLIC ACID OR ITS DERIVATIVES 2013
  • Godlewski Jane Ellen
  • Lingoes Janette Villalobos
  • Collias Dimitris Ioannis
  • Velasquez Juan Esteban
RU2605206C2
METHOD OF PRODUCING ACRYLIC ACID OR DERIVATIVES THEREOF 2013
  • Velasquez Juan Esteban
  • Lingoes Janette Villalobos
  • Collias Dimitris Ioannis
  • Godlewski Jane Ellen
RU2587494C2
PURIFICATION OF BIO-BASED ACRYLIC ACID TO CRUDE AND GLACIAL ACRYLIC ACID 2013
  • Godlewski Jane Ellen
  • Lingoes Janette Villalobos
  • Velasquez Juan Esteban
  • Collias Dimitris Ioannis
RU2599640C2
CATALYTIC CONVERSION OF HYDROXYPROPIONIC ACID OR DERIVATIVES THEREOF INTO ACRYLIC ACID AND DERIVATIVES THEREOF 2013
  • Lingoes Janette Villalobos
  • Velasquez Juan Esteban
  • Godlewski Jane Ellen
  • Collias Dimitris Ioannis
RU2586327C2
CATALYSTS FOR PRODUCING ACRYLIC ACID OR DERIVATIVES THEREOF 2013
  • Velasquez Juan Esteban
  • Lingoes Janette Villalobos
  • Collias Dimitris Ioannis
  • Godlewski Jane Ellen
  • Mamak Marc Andrew
RU2586329C2
CATALYSTS FOR CONVERSION OF HYDROXYPROPIONIC ACID OR DERIVATIVES THEREOF INTO ACRYLIC ACID OR DERIVATIVES THEREOF 2013
  • Velasquez Juan Esteban
  • Lingoes Janette Villalobos
  • Godlewski Jane Ellen
  • Collias Dimitris Ioannis
  • Wireko Fred C.
  • Mamak Marc Andrew
  • Redman-Furey Nancy Lee
RU2591192C2
POLYACRYLIC ACID BASED ON OBTAINED FROM BIOLOGICAL MATERIAL ACRYLIC ACID AND DERIVATIVES THEREOF 2013
  • Godlewski Jane Ellen
  • Lingoes Janette Villalobos
  • Collias Dimitris Ioannis
  • Meyer Axel
  • Dziezok Peter
  • Velasquez Juan Esteban
RU2606124C1
METHOD OF PRODUCING ACRYLIC ACID FROM HYDROXYPROPIONIC ACID 2017
  • Collias, Dimitris, Ioannis
  • Godlewski, Jane, Ellen
  • Velasquez, Juan Esteban
RU2719485C1
CATALYSTS FOR DEHYDRATION OF HYDROXYPROPIONIC ACID AND DERIVATIVES THEREOF 2016
  • Velasquez, Juan, Esteban
  • Collias, Dimitris,Ioannis
  • Godlewski, Jane, Eiien
  • Wireko Fred, Christian
RU2694897C1
CATALYTIC CONVERSION OF LACTIC ACID INTO ACRYLIC ACID 2013
  • Lingoes Janette Villalobos
  • Collias Dimitris Ioannis
RU2598380C2

RU 2 662 229 C2

Authors

Velasquez Juan Esteban

Collias Dimitris Ioannis

Godlewski Jane Ellen

Lingoes Janette Villalobos

Dates

2018-07-25Published

2014-10-16Filed