FIELD: chemistry.
SUBSTANCE: invention relates to methods of converting hydroxypropionic acid, derivatives of hydroxypropionic acid or mixtures thereof into acrylic acid, derivatives of acrylic acid or mixtures thereof. For example, the method involves the following stages: a. aqueous solution containing hydroxypropionic acid, derivatives of hydroxypropionic acid or mixture thereof is prepared, wherein mentioned hydroxypropionic acid is in monomer form in the mentioned water solution; b. mentioned aqueous solution is combined with inert gas to form a mixture of aqueous solution/gas; c. mentioned mixture of aqueous solution/gas is evaporated to obtain a gaseous mixture; d. mentioned gaseous mixture is dehydrated by adding dehydration catalyst to mentioned gaseous mixture under pressure of at least 80 pound/sq. inch gauge. (0.55 MPaG) to produce mentioned acrylic acid, derivatives of acrylic acid or mixtures thereof.
EFFECT: disclosed methods are implemented with high output and selectivity and without significant conversion into undesirable products, such as acetaldehyde, propanoic acid and acetic acid.
34 cl, 1 tbl, 6 ex
Title | Year | Author | Number |
---|---|---|---|
CATALYST FOR PRODUCING BIO-BASED ACRYLIC ACID AND ITS DERIVATIVES AND THE METHOD FOR MAKING THEREOF | 2014 |
|
RU2662229C2 |
METHOD OF PRODUCING ACRYLIC ACID OR DERIVATIVES THEREOF | 2013 |
|
RU2587494C2 |
PURIFICATION OF BIO-BASED ACRYLIC ACID TO CRUDE AND GLACIAL ACRYLIC ACID | 2013 |
|
RU2599640C2 |
CATALYTIC CONVERSION OF HYDROXYPROPIONIC ACID OR DERIVATIVES THEREOF INTO ACRYLIC ACID AND DERIVATIVES THEREOF | 2013 |
|
RU2586327C2 |
CATALYSTS FOR CONVERSION OF HYDROXYPROPIONIC ACID OR DERIVATIVES THEREOF INTO ACRYLIC ACID OR DERIVATIVES THEREOF | 2013 |
|
RU2591192C2 |
POLYACRYLIC ACID BASED ON OBTAINED FROM BIOLOGICAL MATERIAL ACRYLIC ACID AND DERIVATIVES THEREOF | 2013 |
|
RU2606124C1 |
CATALYSTS FOR PRODUCING ACRYLIC ACID OR DERIVATIVES THEREOF | 2013 |
|
RU2586329C2 |
METHOD OF PRODUCING ACRYLIC ACID FROM HYDROXYPROPIONIC ACID | 2017 |
|
RU2719485C1 |
CATALYSTS FOR DEHYDRATION OF HYDROXYPROPIONIC ACID AND DERIVATIVES THEREOF | 2016 |
|
RU2694897C1 |
CATALYSTS FOR PRODUCING ACRYLIC ACID FROM LACTIC ACID OR DERIVATIVES THEREOF IN LIQUID PHASE | 2017 |
|
RU2715707C1 |
Authors
Dates
2016-12-20—Published
2013-04-11—Filed