METHOD OF PREPARATION OF THE CATALYST CARRYING AGENT OF THE DEEP HYDRO-DESULFURIZATION OF THE VACUUM GAS-OIL Russian patent published in 2018 - IPC B01J37/00 B01J21/02 B01J21/12 B01J35/04 

Abstract RU 2663901 C1

FIELD: chemistry.

SUBSTANCE: invention relates to catalytic chemistry, in particular to the preparation of catalyst carriers for deep hydrodesulfurization of vacuum gas oil, and can be used in the oil refining industry. Method for the preparation of a catalyst for deep hydrodesulfurization of a vacuum gas oil is described, comprising the preparation of a mixture comprising aluminum, in the form of aluminum, hydroxide in the form of boehmite and aluminum, in the form of mesoporous aluminosilicate, mixing and suspending the resulting mixture, introducing a solution of nitric acid, stirring to obtain a homogeneous mass, introducing a pore-forming agent, stirring to a homogeneous state, molding extrusion pellet, drying and calcination, differs that a mixture is prepared by successively mixing aluminic oxide obtained by treating aluminum hydroxide with 1–5 % solution of nitric acid at solution temperature of 5–10 °C and spray dried in hot air at temperature of 150–210 °C, with aluminic oxide in the form of mesoporous aluminosilicate, and thoroughly mixing, and aluminic oxide as boehmite is introduced into the resulting mixture, providing a weight ratio in the carrier SiO2:Al2O3 = 0.09:0.19, herewith triglycol is used as the pore-forming agent.

EFFECT: increasing the mechanical strength and specific surface of the carrier, sufficient to produce high-value catalysts for deep hydrodesulfurization of vacuum gas oil, increasing the activity and stability of the catalyst, that leads to an increase in the degree of hydrogenolysis of organosulfur compounds, increase in yield and selectivity for the target product in the subsequent catalytic cracking process of vacuum gas oil.

1 cl, 1 tbl, 3 ex

Similar patents RU2663901C1

Title Year Author Number
CATALYST OF DEEP HYDRODESULFURIZATION OF VACUUM GASOIL AND METHOD OF ITS PREPARATION (VARIANTS) 2018
  • Morozova Yanina Vladislavovna
  • Loginova Anna Nikolaevna
  • Arkhipova Irina Aleksandrovna
  • Bakanev Ivan Alekseevich
  • Fadeev Vadim Vladimirovich
RU2666733C1
CATALYST FOR HYDRO-SKIMMING VACUUM GAS OIL AND PREPARATION METHOD THEREOF (VERSIONS) 2015
  • Loginova Anna Nikolaevna
  • Mikhajlova Janina Vladislavovna
  • Isaeva Ekaterina Alekseevna
  • Krukovskij Ilja Mikhajlovich
  • Safatova Irina Aleksandrovna
RU2605939C2
CATALYST FOR VACUUM GAS OIL HYDROTREATING, AND PROCESS FOR PREPARATION (VERSIONS) 2016
  • Loginova Anna Nikolaevna
  • Morozova Yanina Vladislavovna
  • Kashkina Elena Ivanovna
  • Leontev Aleksej Nikolaevich
  • Arkhipova Irina Aleksandrovna
  • Fadeev Vadim Vladimirovich
RU2616601C1
CATALYST FOR VACUUM GAS OIL HYDROTREATING AND METHOD OF PREPARATION THEREOF 2016
  • Morozova Yanina Vladislavovna
  • Loginova Anna Nikolaevna
  • Leontev Aleksej Nikolaevich
  • Arkhipova Irina Aleksandrovna
  • Sviderskij Sergej Aleksandrovich
  • Fadeev Vadim Vladimirovich
RU2620267C1
CATALYST, METHOD OF PRODUCING SUPPORT, METHOD OF PRODUCING CATALYST AND METHOD OF HYDROFINING HYDROCARBON MATERIAL 2011
  • Klimov Oleg Vladimirovich
  • Korjakina Galina Ivanovna
  • Budukva Sergej Viktorovich
  • Leonova Ksenija Aleksandrovna
  • Perejma Vasilij Jur'Evich
  • Dik Pavel Petrovich
  • Noskov Aleksandr Stepanovich
  • Parakhin Oleg Afanas'Evich
RU2472585C1
METHOD OF PRODUCING CATALYST SUPPORT FOR CONVERSION OF HYDROCARBON RAW MATERIAL BASED ON MESOPOROUS MATERIAL 2015
  • Fadeev Vadim Vladimirovich
  • Lysenko Sergej Vasilevich
  • Loginova Anna Nikolaevna
RU2584951C1
METHOD OF PROCESSING HEAVY HYDROCARBON MATERIAL USING SULFUR-REDUCING ADDITIVES TO CRACKING CATALYSTS 2019
  • Levshakov Nikolaj Sergeevich
  • Akopyan Argam Vilikovich
  • Anisimov Aleksandr Vladimirovich
  • Andreev Boris Vladimirovich
  • Ustinov Andrej Stanislavovich
  • Karakhanov Eduard Avetisovich
RU2711568C1
METHOD OF PREPARING CATALYST FOR MILD HYDROCRACKING OF OIL STOCK 1997
  • Irisova K.N.
  • Smirnov V.K.
  • Chvanova E.S.
  • Karel'Skij V.V.
  • Aseeva A.P.
RU2124400C1
SINGLE-STEP METHOD FOR MILD HYDROCRACKING OF PETROLEUM RAW MATERIALS 1997
  • Smirnov V.K.
  • Motov M.V.
  • Irisova K.N.
  • Karel'Skij V.V.
RU2124042C1
VACUUM GAS OIL HYDROPROCESSING METHOD 2023
  • Lysikov Anton Igorevich
  • Shamanaeva Irina Alekseevna
  • Vorobeva Ekaterina Evgenevna
  • Polukhin Aleksandr Valerevich
  • Vdovichenko Vsevolod Aleksandrovich
  • Maslenkin Roman Alekseevich
  • Parkhomchuk Ekaterina Vasilevna
RU2813488C1

RU 2 663 901 C1

Authors

Morozova Yanina Vladislavovna

Loginova Anna Nikolaevna

Arkhipova Irina Aleksandrovna

Fadeev Vadim Vladimirovich

Dates

2018-08-13Published

2018-01-18Filed