FIELD: physics.
SUBSTANCE: invention relates to a technology for producing a scintillational crystalline material for radiation detectors used for positron emission tomography (PET), X-ray computed tomography (CT), various radimeters in the field of high energy physics, resource-extraction devices. Crystalline material is represented by general chemical formula (RExA1-x-y-sByM's)2+α(Si1-t,M''t)2+βO7+γ, has a pyrochlore type structure, has a non-stoichiometric composition and is a congruent melting compound. In the chemical formula, A contains at least one or more, selected from Gd, Y, La, Sc, Yb and Lu; B comprises at least one or more, selected from La, Gd, Yb, Lu, Y and Sc; 0.1 < y < 0.4; RE contains at least one or more selected from Ce, Pr, Nd, Eu, Tb and Yb; 0 < x < 0.1; M' and M'' contain at least one or more, selected from Li, Na, K, Mg, Ca, Sr, Ba, Ti, Zr, Hf, Fe, Ta and W; 0 ≤ s < 0.01 and 0 ≤ t < 0.01; and 0 < |α| < 0.3, and 0 ≤ |β| < 0.3, and 0 ≤ |γ| < 0.5.
EFFECT: resulting material has a high-quality transparent volumetric body, has a large glow and a short fluorescence lifetime.
15 cl, 14 dwg, 3 tbl
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Authors
Dates
2018-09-07—Published
2016-05-27—Filed