FIELD: oil and gas industry.
SUBSTANCE: invention relates to a process for production of petroleum sulfoxides that are used as extractants of noble metals, flotation agents – ore collectors, active biological substances, etc. Method includes oxidizing sulfides of sulfurous oils and isolating the desired products, as an oxidizer, an industrial aqueous solution of chlorine dioxide with concentration of 5 g/l and consumption per gram sulfur atom of sulfide equal to 0.5–1.0 mole is used, oxidant is fed into the concentrate at temperature of 20°°C by addition of ClO2 or by bubbling with air, oxidation product is extracted with chloroform, washed to neutral, dried over MgSO4, chloroform is distilled off in vacuo at 20°°C.
EFFECT: method for preparation of petroleum sulfoxides is proposed.
1 cl, 3 tbl, 1 ex
Title | Year | Author | Number |
---|---|---|---|
SULFOXIDE MIXTURE PRODUCTION | 2002 |
|
RU2221779C2 |
LIGHT PETROLEUM DISTILLATE DESULFURIZATION METHOD | 2002 |
|
RU2235112C1 |
METHOD OF PREPARING SULFOXIDES | 1999 |
|
RU2144025C1 |
METHOD OF PREPARING SULFOXIDES | 1998 |
|
RU2139275C1 |
PETROLEUM SULFIDE OXIDATION PROCESS | 2005 |
|
RU2291859C1 |
METHOD OF SYNTHESIS OF SULFOXIDES | 1997 |
|
RU2127258C1 |
METHOD FOR PREPARING SULFOXIDES | 2002 |
|
RU2234498C2 |
PROCESS FOR PRODUCTION OF LOW SULFUR-CONTENT DISTILLATES FROM LIQUID HYDROCARBON FEEDSTOCK | 2002 |
|
RU2235111C1 |
METHOD OF PURIFICATION OF OIL PRODUCTS FROM SULFIDES | 1999 |
|
RU2160302C1 |
METHOD OF BULK FLOTATION OF SULFIDES CONTAINING NOBLE METALS FROM COMPLEX-ORE IRON-CONTAINING MATERIALS | 1995 |
|
RU2100095C1 |
Authors
Dates
2018-10-08—Published
2017-08-07—Filed