FIELD: oil and gas industry.
SUBSTANCE: invention relates to an improved method for reducing trace amounts of mercury in crude oil feedstock, which comprises passing crude oil feedstock characterised by a certain a mercury concentration, as feed stream to a filtration device having at least a filter element to generate a filtered crude having a reduced concentration of mercury, and a reject stream containing crude oil having a concentrated of mercury level of at least 10 times the concentration of mercury in the crude oil feed; mixing into the reject stream an effective amount of an extractive agent to remove at least a portion of the mercury for a treated crude oil having a reduced concentration of mercury; wherein the extractive agent is selected from the group of oxidising agents; reducing agents, organic or inorganic sulphides with at least one sulphur atom reactive with mercury; tetrakis(hydroxymethyl)phosphonium sulphate; tetrakis(hydroxymethyl)phosphonium chloride; and combinations thereof. Invention also relates to an improved method for reducing the trace amount of mercury in a crude oil feedstock comprising passing crude oil feedstock having a certain mercury concentration, through a filtration device with a filter element, to retain at least 50 % of the mercury on the filter element and generate a filtered crude having a reduced concentration of mercury; back-flushing the filtration device with a portion of the filtered crude to generate a reject stream containing crude oil having a concentrated mercury level of at least 20 times the concentration of mercury in the fed crude; mixing into the reject stream an effective amount of an extractive agent to convert at least a portion of the mercury into volatile mercury; removing a portion of the volatile mercury using one of the following methods: stripping, scrubbing, adsorption and combinations thereof to obtain a treated crude oil having a reduced concentration of mercury.
EFFECT: process, a method and a system for removing heavy metals from fluids are proposed.
17 cl, 5 ex, 2 tbl, 1 dwg
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING SYNTHESIS GAS | 1994 |
|
RU2085477C1 |
METHOD FOR SELECTIVE EXTRACTION OF TRANSITION METALS FROM ORGANIC RESIDUES | 2019 |
|
RU2804748C2 |
METHOD FOR GAS FLOW PURIFICATION | 2011 |
|
RU2567301C2 |
METHOD FOR PREPARING HIGH-PURITY CRYSTALLINE INSULIN OF ANY ORIGIN | 2011 |
|
RU2453331C1 |
DEVICE FOR TREATMENT OF WATER | 2001 |
|
RU2241521C1 |
SORBENT | 2010 |
|
RU2536989C2 |
METHOD OF PRODUCING HEMICELLULOSE EXTRACTS | 2017 |
|
RU2736368C2 |
CALCIUM REMOVAL FROM CRUDE OIL METHOD | 2006 |
|
RU2379330C1 |
COMPOSITIONS OF MIXED DECYLMERCAPTANS AND THEIR USE FOR EXTRACTION OF CHEMICAL SUBSTANCES DURING EXTRACTION OF MINERALS | 2016 |
|
RU2715577C2 |
PROCESS FOR REMOVAL SULFUR FROM RAW METHANOL | 2014 |
|
RU2672732C2 |
Authors
Dates
2018-11-01—Published
2014-03-04—Filed