FIELD: metallurgy.
SUBSTANCE: invention relates to the field of metallurgy, in particular to invar alloys and compositions, characterized by the value of the coefficient of linear thermal expansion (CLTE), not exceeding 2 × 10-6 K-1 in the working temperature range, and can be used in instrument making, radio electronics, aviation and aerospace, laser and cryogenic engineering. Composite material with invar properties contains a functional metal with an average CLTE value not exceeding 13 × 10-5 K-1 in the range of temperatures 4.5–32 K or 3.22 × 10-5 K-1 in the temperature range of 32–250 K, and a compound with negative CLTE, while a samarium-based valence-unstable compound (VUC) is used as a compound with negative CLTE, the quantitative ratio of the composite components is determined from the Turner condition: (αƒVƒKƒ + αmVmKm) / (VƒKƒ + VmKm) = 0, where: αm – CLTE functional metal, αƒ – CLTE valence-unstable compound, Vm and Vƒ – volume fractions of metal and VUC, respectively; Km and Kƒ – bulk moduli of metal and VUC, respectively.
EFFECT: invention is directed to the creation of a composite material with a CLTE close to zero in the temperature range up to 250 K while preserving in the composite the physical properties inherent in the metal component.
3 cl, 2 dwg, 2 tbl
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Authors
Dates
2019-01-09—Published
2017-09-06—Filed