FIELD: technological processes.
SUBSTANCE: invention relates to a method of recovering activity of a zeolite-containing catalyst for isodeparaffinising diesel fuel in the presence of a hydrogen-containing gas and can be used in oil refining. Disclosed is a method of reducing activity of a zeolite-containing catalyst at high temperature and pressure, including a step for processing a hydrogen-containing gas, wherein the zeolite-containing catalyst used is a nickel-molybdenum catalyst for diesel isodeparaffinification process, which is first subjected to treatment with a light hydrocarbon fraction in a circulating hydrogen-containing gas medium, with subsequent two-step treatment with hydrogen-containing gas, wherein hydrogen-containing gas is a mixture of hydrogen-containing gas and hydrogen sulphide with hydrogen sulphide content of 0.2–0.4 vol%.
EFFECT: method allows almost complete recovery of initial activity of a zeolite-containing nickel-molybdenum catalyst, as well as longer service life of the catalyst before oxidative regeneration.
3 cl, 1 tbl, 3 ex
| Title | Year | Author | Number | 
|---|---|---|---|
| IZODEWAXING CATALYST AND A METHOD FOR PRODUCING LOW-SOLIDIFICATION DIESEL FUELS WITH ITS USE | 2017 | 
 | RU2662934C1 | 
| METHOD FOR HYDROTREATING SECONDARY DISTILLATES | 2023 | 
 | RU2824346C1 | 
| METHOD OF RECOVERING ACTIVITY OF A ZEOLITE-CONTAINING CATALYST | 2019 | 
 | RU2714677C1 | 
| METHOD OF PRODUCING SWEETENED DIESEL FUEL WITH SUPER LOW CONTENTS OF SULPHUR | 2008 | 
 | RU2362797C1 | 
| METHOD FOR HYDROGENATION TREATMENT OF VEGETABLE AND OIL RAW MATERIALS | 2019 | 
 | RU2741302C1 | 
| METHOD OF OBTAINING MOTOR FUEL | 2016 | 
 | RU2623088C1 | 
| METHOD OF PRODUCING REACTIVE AND DIESEL FUELS FROM MIXTURE OF VEGETABLE AND OIL RAW MATERIALS | 2019 | 
 | RU2737724C1 | 
| METHOD TO PRODUCE WAXY TEMPERATURE-STABLE HYDROCARBON FRACTIONS | 2012 | 
 | RU2561918C2 | 
| METHOD FOR PROCESSING OIL RESIDUES | 2017 | 
 | RU2671640C1 | 
| HYDROGENATION REFINEMENT METHOD OF HYDROCARBON MATERIAL | 2018 | 
 | RU2691067C1 | 
Authors
Dates
2019-06-07—Published
2019-02-11—Filed