FIELD: technological processes.
SUBSTANCE: invention relates to curable polymer compositions which contain photo-polymerizable components which are curable by ultraviolet radiation to form cured products. Disclosed is a curable polymer composition comprising a thermo-polymerizable component which is a phenol-formaldehyde resin, a modified propargyl halide (20.0–40.0 wt%), and a photopolymer composition which contains (wt%): triethylene glycol dimethacrylic ester (5–20), styrene (14–19), bisphenol A based vinyl ester resin or based on novolac phenol-formaldehyde resin (35.0–50.0) and photoinitiator (0.5–1.0). Also disclosed is a method of producing a solidified product from said curable polymer composition.
EFFECT: disclosed composition is stable during storage and enables the disclosed method to obtain articles with improved heat resistance.
7 cl, 1 tbl, 5 ex
| Title | Year | Author | Number | 
|---|---|---|---|
| NON-FLAMMABLE PHOTOPOLYMERIZABLE COMPOSITION FOR 3D PRINTING | 2022 | 
 | RU2799565C1 | 
| PROCESS OF MODULAR PHOTOPOLYMERIZATION, PHOTOPOLYMERIZING COMPOSITION | 1994 | 
 | RU2138070C1 | 
| LIQUID PHOTOPOLYMERISED COMPOSITION FOR LASER STEREOLITHOGRAPHY | 2008 | 
 | RU2395827C2 | 
| LIQUID PHOTOPOLYMERIZABLE COMPOSITION FOR LASER STEREOLITHOGRAPHY | 2017 | 
 | RU2685211C2 | 
| ANTIMONY-FREE PHOTOCURABLE POLYMERIC COMPOSITION AND THREE-DIMENSIONAL ARTICLE | 2006 | 
 | RU2408627C2 | 
| PHOTOPOLYMER COMPOSITION FOR THE PRODUCTION OF THERMAL-RESISTANT OBJECTS BY THE METHOD OF LASER STEREOLITHOGRAPHY | 2017 | 
 | RU2684387C2 | 
| PHOTOPOLYMERIZING COMPOSITION | 2021 | 
 | RU2773188C1 | 
| COMPOSITION AND METHOD FOR ITS HARDENING | 1997 | 
 | RU2210798C2 | 
| PHOTOCURABLE COMPOSITIONS FOR MAKING ABS-LIKE ARTICLES | 2006 | 
 | RU2431879C2 | 
| POLYMER COMPOSITION, METHOD FOR ITS PREPARATION AND POLYMERIZATION | 2023 | 
 | RU2818758C1 | 
Authors
Dates
2019-09-06—Published
2019-03-18—Filed