FIELD: chemistry.
SUBSTANCE: group of inventions relates to drilling fluids and a method for production thereof. Method of producing drilling fluid involves oligomerisation of hex-1-ene to form oligomers, which include trimers and tetramers of hex-1-ene with ratio of trimer to tetramer of more than 1:1 and content of trimers of more than 30 wt. %, wherein oligomers are formed in the presence of acid-type catalysts; mixing said oligomers with linear olefins which include linear alpha-olefins and/or linear internal olefins with 6 to 30 carbon atoms. Drill mud obtained by said method contains linear olefins which include linear alpha-olefins and/or linear internal olefins with number of carbon atoms from 6 to 30; and oligomers, which include dimers, trimers, tetramers and/or heavier oligomers of olefins, wherein said oligomers include trimers and tetramers of hex-1-ene with ratio of trimer to tetramer greater than 1:1 and content of trimers more than 30 wt. % and where said oligomers include at least 50 mol percent trisubstituted olefin. Drilling fluid has pour point -10 °C or lower, biodegradation index 1.0 or lower, toxicity index 1.0 or lower, indicator in Marine BODIS test is at least 60 %, flash point is 110 °C or higher, content of olefins 90 wt. % or higher, viscosity less than 4 cSt at 40 °C, density from 0.78 to 0.83 g/ml and distribution coefficient in system octanol/water log Pow higher than 3.
EFFECT: technical result is low pour point, biodegradation and low toxicity of drilling mud.
24 cl, 8 dwg, 7 tbl, 14 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PREPARING REVERSED DRILLING MUD CONTAINING MIXTURES OF SECONDARY ESTERS PRODUCED BY CONVERSION OF OLEFINS | 1998 |
|
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METHOD OF PRODUCING BASE OIL | 2007 |
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RU2427564C2 |
OLIGOMERIZATION OF ALPHA-OLEFINS USING CATALYTIC METALLOCENE-TSK SYSTEMS AND USE OF OBTAINED POLYALPHAOLEFINS FOR PRODUCTION OF LUBRICATING MIXTURES | 2013 |
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RU2649390C2 |
METHOD OF PRODUCING OLEFIN OLIGOMERS | 2007 |
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RU2437920C2 |
LOW-VISCOSITY OIL FROM OLIGOMERS, METHOD OF OBTAINING THEREOF AND THEREOF-CONTAINING COMPOSITION | 2008 |
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METHOD OF PRODUCING OLIGOMERS OF HIGHER LINEAR ALPHA-OLEFINS | 2011 |
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RU2483052C2 |
SYNTHETIC FLUIDS WITH IMPROVED BIODEGRADABILITY | 2019 |
|
RU2804659C2 |
ALKENE OLIGOMERS PRODUCTION PROCESS | 2000 |
|
RU2177930C1 |
METHOD OF PRODUCING OLIGOMERS OF HIGHER LINEAR α-OLEFINS | 2011 |
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RU2483053C2 |
METHOD OF PRODUCING OLIGOMERS OF HIGHER LINEAR α-OLEFINS | 2011 |
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RU2487112C2 |
Authors
Dates
2019-12-06—Published
2015-05-04—Filed