FIELD: chemical or physical processes.
SUBSTANCE: invention relates to a method of producing a catalyst for selective catalytic reduction of NOx containing a zeolitic material, said zeolite material containing one or more zeolites, GME having a carcass structure comprising YO2 and X2O3, and further comprises one or more zeolites having the CHA framework structure comprising YO2 and X2O3, where Y represents Si, and wherein X represents Al, and wherein said method comprises: (i) preparing a mixture comprising at least one source of YO2,at least one source of X2O3 and optionally containing seed crystals; (ii) crystallizing the mixture obtained in step (i) to obtain a zeolite material containing one or more zeolites having a GME framework structure and further containing one or more zeolites, having carcass structure CHA; (iii) recovering zeolite material obtained at step (ii); (iv) washing zeolite material obtained at step (iii); (v) drying the zeolite material obtained at step (iv); (vi) exposing the zeolitic material obtained at step (v) to an ion exchange method, wherein at least one ionic frameless element or compound contained in the zeolite material is subjected to ion exchange for Cu. Invention also relates to catalysts (versions) for selective catalytic reduction of NOx, to a method for selective catalytic reduction of NOx and use of the catalyst.
EFFECT: technical result is improved NOx conversion activity.
8 cl, 6 dwg, 1 tbl, 8 ex
Title | Year | Author | Number |
---|---|---|---|
ORGANOTEMPLATE-FREE SYNTHETIC PROCESS FOR PRODUCTION OF A ZEOLITIC MATERIAL OF CHA-TYPE STRUCTURE | 2012 |
|
RU2612697C2 |
ZEOLITE MATERIALS OF SLEEP TYPE AND METHODS OF THEIR PRODUCTION WITH THE USE OF CYCLOALKYLAMMONIUM COMPOUNDS | 2013 |
|
RU2627399C2 |
CHA TYPE ZEOLITIC MATERIALS AND METHODS FOR THEIR PREPARATION USING COMBINATIONS OF CYCLOALKYL- AND TETRAALKYLAMMONIUM COMPOUNDS | 2015 |
|
RU2678676C2 |
ZEOLITE MATERIAL POST-TREATMENT | 2013 |
|
RU2637021C2 |
POST-TREATMENT OF DEBORATED ZEOLITE BETA | 2013 |
|
RU2636724C2 |
POST-TREATMENT OF DEBORATED ZEOLITE MWW | 2013 |
|
RU2638851C2 |
ZEOLITE MATERIALS, AND MANUFACTURING METHODS USING ALCENYILTRIAMMONIUM COMPOUNDS | 2013 |
|
RU2622300C2 |
METHOD OF PRODUCING ZEOLITE MATERIAL USING ELEMENTARY PRECURSORS | 2013 |
|
RU2636085C2 |
ZEOLITES ZSM-5 AND ZSM-11 SYNTHESIS | 2000 |
|
RU2243156C2 |
ALUMOSILICATE ZEOLITE, CONTAINING TRANSITION METAL | 2009 |
|
RU2535706C2 |
Authors
Dates
2021-01-14—Published
2017-06-02—Filed