FIELD: chemistry.
SUBSTANCE: invention relates to azolin compounds of formula I, where X1 is O; A is group 2; where A 2 represents a group -C(R7a)(R7b)-N(R52)-C(=O)-R62; B1, B2, B3, B4 and B5 independently represent CR2; Rg1 and Rg2 together form a bridging group selected from a group consisting of -CH2CH2O-, -OCH2CH2-, -CH2OCH2-, -OCH2O-, -CH2CH2S(O)p-, -S(O)pCH2CH2-, -CH2S(O)pCH2-, -OCH2CH2CH2- and -CH2CH2CH2O-; where p is 0, 1 or 2; R1 is C1-haloalkyl; each R2 is independently selected from a group consisting of hydrogen, halogen and C1-C2-haloalkyl; R3a and R3b are hydrogen; R7a and R7b are hydrogen; R52 is selected from a group consisting of hydrogen, C1-C3-alkyl and C1-C6-alkoxymethyl; R62 is selected from a group consisting of C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkyl, substituted with one or two radicals R82, C1-C6-haloalkyl, which carries one radical R82, C2-C6-alkynyl, C3-C6-cycloalkyl, which optionally carries CN substitute, C3-C6-halocycloalkyl, -CH=NOR92 and heterocyclic ring, selected from a group consisting of rings of formulas E-43–E-63 (see claim 1), where in the rings E-43–E-63 the broken line represents a point of attachment to the remaining molecule; k is 0, 1, 2 or 3; n is 0, 1 or 2; and R16 has values given below; each R82 is independently selected from a group consisting of C3-C6-cycloalkyl, which optionally carries CN substitute; C3-C6-halocycloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkylthio, C1-C6-haloalkylthio, C1-C6-alkylsulfinyl, C1-C6-haloalkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkylsulfonyl, and heterocyclic ring, selected from a group consisting of rings E-43 to E-63, as defined above; R92 is selected from C1-C6-alkyl and C1-C6-haloalkyl; and each R16 is independently selected from a group consisting of C1-C4-alkyl and C1-C4-haloalkyl; or two R16, present on same carbon atom of saturated ring, can together form =O; and stereoisomers thereof and agriculturally or veterinarily acceptable salts. Invention also relates to an insecticidal or arachnid composition based on said compounds.
EFFECT: technical result is obtaining novel compounds which can be used in agriculture for controlling invertebrate pests.
17 cl, 3 tbl, 7 ex
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