FIELD: polymers.
SUBSTANCE: group of inventions relates to methods for efficient blowing of polymer particles in a gas-phase fluidized bed reactor. The method includes polymerizing olefinic monomers and optionally comonomers in a first reactor vessel to form a crude product stream containing polymerized solids, unreacted monomer, and optionally comonomer, the polymerized solid particles containing olefinic polymer, VOCs and catalyst system, bringing polymerized solid particles into contact with a catalytic poison selected from carbon monoxide, carbon dioxide, oxygen, water, alcohols, amines, or mixtures thereof, thus forming a passivated stream, while deactivating the catalytic system, maintaining the passivated stream in a mixed state in the second reactor and bringing the passivated stream in the second reactor into contact with a circulating gas containing unreacted monomer present in an amount from 50.0 to 99.5 wt % of the total mass of the circulating gas, during stay, thus reducing the concentration of VOCs in the polymerized solid particles by at least 10% of the mass compared to the level upstream of the second reactor, thus forming a stream of purified olefinic polymer solid particles.
EFFECT: blowing methods provide improved removal of volatile organic compounds (VOCs) generated during polymer production.
31 cl, 2 dwg, 2 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PRODUCING PROPYLENE COPOLYMERS WITH LOW VOC CONTENT | 2018 |
|
RU2781427C2 |
METHOD OF CONTINUOUS GAS PHASE POLYMERIZATION OF ALFA- OLEFIN(S) | 1994 |
|
RU2125063C1 |
SYSTEMS AND METHODS OF POLYMER PRODUCTION | 2009 |
|
RU2533488C2 |
SYSTEMS AND METHODS OF PRODUCING POLYMERS | 2009 |
|
RU2531959C2 |
LATENT MATALLOCENE CATALYTIC SYSTEMS FOR POLYMERIZATION | 2002 |
|
RU2307838C2 |
OLEFIN GAS PHASE POLYMERISATION METHOD | 2018 |
|
RU2739304C1 |
TREATMENT METHOD OF POLYOLEFIN PARTICLES PRODUCED BY GAS-PHASE POLYMERIZATION | 2013 |
|
RU2600550C1 |
LATENT METALLOCENE CATALYTIC SYSTEMS FOR OLEPHINE POLYMERISATION | 2002 |
|
RU2330862C2 |
GAS-PHASE METHOD OF POLYMERISATION OF PROPYLENE | 2016 |
|
RU2721530C2 |
CONTROLLING H DISTRIBUTION IN HORIZONTAL STIRRED BED REACTOR | 2011 |
|
RU2554093C2 |
Authors
Dates
2021-06-29—Published
2017-09-11—Filed