METHOD FOR CONTINUOUS PROMOTION OF A TITANIUM-MAGNESIUM ZIEGLER-NATTA CATALYST IN THE PROCESSES OF OLEFIN (CO)POLYMERISATION Russian patent published in 2021 - IPC B01J37/00 B01J21/00 C08F10/00 C08F4/654 

Abstract RU 2759723 C1

FIELD: polymers.

SUBSTANCE: invention relates to the polymer industry, specifically, to the olefin polymerisation processes occurring on Ziegler-Natta catalytic systems based on a solid Ti-Mg component in the presence of organoaluminium compounds. Described is a method for maintaining the catalytic activity of a titanium-magnesium component in the olefin (co)polymerisation processes, including supplying a Ziegler-Natta catalyst, an organoaluminium co-catalyst and a chlorine-containing hydrocarbon to the process, characterised by the fact that when supplying to the polymerisation process, a hydrocarbon with a content of carbon atoms of 6 and higher and with a content of chlorine atoms of 3 to 6 is used as a chlorine-containing hydrocarbon, selected from the group consisting of trichlorotoluene, hexachlorparaxylene or mixtures thereof, wherein the chlorine-containing hydrocarbon is introduced into the polymerisation process in the same solvent as the titanium-magnesium component, at the molar ratio of the chlorine-containing compound (by Cl) : titanium=0.1÷10:1.

EFFECT: development of an efficient method for maintaining the activity of a catalytic system based on a solid titanium-magnesium component in the processes of olefin (co)polymerisation.

4 cl, 4 tbl, 2 dwg, 20 ex

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Authors

Salakhov Ildar Ilgizovich

Sakhabutdinov Anas Gaptynurovich

Batyrshin Ajrat Zajtunovich

Shajdullin Nadim Marselevich

Borodin Ruslan Gennadevich

Mikhajlov Vyacheslav Nikolaevich

Nazarov Valerij Vyacheslavovich

Khakimova Tatyana Mikhajlovna

Volkov Vladislav Leonidovich

Suslova Tatyana Nikolaevna

Dates

2021-11-17Published

2020-12-23Filed