CO-PRODUCTION OF MONOMERS, INCLUDING AT LEAST ONE BIO-BASED MONOMER Russian patent published in 2023 - IPC C07C51/265 C07C63/26 C07C51/235 C07B33/00 C07B41/08 C07B41/12 C07D307/68 B01J23/34 B01J23/75 

Abstract RU 2799207 C2

FIELD: chemical industry.

SUBSTANCE: invention relates to method for obtaining a composition based on a mixture of monomers containing 2,5-furandicarboxylic acid (FDCA) and terephthalic acid (TPA). The method includes the dehydration of one or more six-carbon carbohydrates to obtain furan compounds forming FDCA, and the joint supply of these compounds and para-xylene to an oxygen oxidation reactor in the presence of an oxidation catalyst containing cobalt and (or) manganese compounds.

EFFECT: method for co-processing in the form of acid dehydration of renewable hexoses or hexosans to obtain 5-hydroxymethylfurfural (HMF), further co-catalytic oxidation of HMF and fossil raw materials in the form of p-xylene to obtain a composition of a mixture of monomers containing FDCA and TPA, reducing production energy costs in such joint processing, as well as reducing the poisoning of the catalytic system by side humins.

10 cl, 5 dwg, 2 tbl

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RU 2 799 207 C2

Authors

Ingram Andrew

Hagberg Erik

Ma Chi-Cheng

Mcclurg Jessica

Stensrud Kenneth

Dates

2023-07-04Published

2021-05-12Filed