CATALYST FOR HYDROGENATION OF DICYCLOPENTADIENE Russian patent published in 2023 - IPC B01J23/83 B01J23/755 B01J23/10 B82B3/00 C07C5/03 C07C13/54 

Abstract RU 2799451 C1

FIELD: catalysts.

SUBSTANCE: invention relates to a catalyst for the exhaustive hydrogenation of dicyclopentadiene in the form of nickel particles nanostructured on porous γ-Al2O3 granules by impregnation of the carrier with an aqueous solution of nickel chloride hexahydrate and reduction with an aqueous solution of sodium tetrahydroborate. The method is characterized by the fact that the surface of γ-Al2O3 is pre-coated with cerium dioxide applied by hydrothermal treatment at 95-120°C for 2 h in an aqueous solution of 0.005 mol/l cerium nitrate and 0.05 mol/l urea and additional heat treatment at 400°C for 1 hour.

EFFECT: catalyst is efficient, has an increased specific productivity, and also makes it possible to reduce the conditional residence time of the components in the reactor.

2 cl, 1 tbl, 4 ex

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RU 2 799 451 C1

Authors

Nebykov Denis Nikolaevich

Simonenko Nikolai Petrovich

Simonenko Tatiana Leonidovna

Panov Aleksandr Olegovich

Mokhov Vladimir Mikhailovich

Dates

2023-07-05Published

2022-12-20Filed