FIELD: materials science.
SUBSTANCE: invention relates to the technology for producing phosphates, oxophosphates and vanadium fluoride phosphates, which can be used as active electrode materials for metal-ion batteries. Compositions AV1-xMxPO4(F1-yOy) are considered as electrochemical active compounds, and composites with carbon based on the same compositions AV1-xMxPO4(F1-yOy)/C are considered as a component of the electrode mixture, where A=Li, Na, K or a mixture thereof, M is one of the following metals: Ti, Cr, Mn, Fe, Al, Sc, Zn or a mixture thereof, with 0≤X≤10≤y≤1. To obtain these compounds, a two-stage chemical technology is used. The first step involves preparing the precursor by treating the reaction mixture under hydrothermal or solvothermal conditions. At the second stage, a chemical reaction is carried out between the resulting precursor and a lithium, sodium or potassium salt at elevated temperatures.
EFFECT: increasing the manufacturability of the process, reducing the load on the environment and treatment facilities, as well as the ability to effectively control the morphology of particles and the fluorine-oxygen ratio during the synthesis process.
8 cl, 6 dwg, 20 ex
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Authors
Dates
2023-09-26—Published
2023-03-07—Filed