FIELD: production of fluorescent diamonds.
SUBSTANCE: invention is related to a method for producing fluorescent diamond containing an MV centre in a concentration of 1×1014/cm3 or higher, where M is selected from a metal or metalloid such as Si, Ge, Sn, Pb, Ni or Co, and V represents a vacancy. The first stage involves the synthesis of diamond by chemical vapor deposition (CVD) or detonation, for example an inward explosion, introducing from 0.0001 to 1 at% of the specified metal or metalloid and additionally ensuring the presence of a metal or metalloid other than M, for example Fe, Co or Ni. In the second stage, the resulting diamond containing M is irradiated with a high-energy beam, for example a beam of He or H ions, or an electron beam to form the V vacancy. After this, the diamond is annealed to form a fluorescent MV centre.
EFFECT: resulting fluorescent diamond is characterized by high luminous efficiency and low background fluorescence due to the specified concentration of MV centres and M content, as well as due to the V to M ratio from 0.1 to 10,000; concentration of nitrogen-vacancy centres (NV-centers) 1×1017/cm3 or lower and vacancy densities from 1×1016 to 3×1021/cm3.
12 cl, 14 dwg, 3 ex
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Authors
Dates
2023-10-02—Published
2019-10-29—Filed