FIELD: oil industry.
SUBSTANCE: group of inventions relates to the oil refining industry and can be used to increase the octane number of catalytically cracked gasoline. Disclosed catalyst includes ultrastable zeolite Y in cation-decationated form and a matrix consisting of amorphous aluminosilicate, aluminium oxide and natural clay, wherein matrix components used are modified aluminosilicate containing 0.05–5 wt.% oxides of rare-earth elements, modified aluminium oxide containing 0.05–3 wt.% oxides of rare-earth elements, and natural clay with the following content of components in the catalyst, wt.%: zeolite Y 20–24; amorphous aluminosilicate 30–40; aluminium oxide 24–30; natural clay 7–24. Proposed catalyst preparation method involves ion exchanges for cations of rare-earth elements and ammonium on NaY zeolite, two-step ultrastabilization of zeolite, mixing zeolite with a matrix, components of which are amorphous aluminosilicate, aluminium oxide and natural clay, spray drying of the obtained composition, followed by calcination and obtaining a catalyst, wherein amorphous aluminosilicate is modified by activation with solution of nitrate salts of rare-earth elements to content of oxides of rare-earth elements of 0.05–5 wt.%, aluminium oxide is modified by hydrothermal treatment in the presence of a solution of nitrate salts of rare-earth elements to content of oxides of rare-earth elements of 0.05–3 wt.%. with the following content of components in the catalyst, wt.%: zeolite Y 20–24; amorphous aluminosilicate 30–40; aluminium oxide 24–30; natural clay 7–24.
EFFECT: obtaining an efficient vacuum gas oil cracking catalyst for obtaining gasoline with high octane characteristics.
6 cl, 1 tbl, 12 ex
| Title | Year | Author | Number | 
|---|---|---|---|
| MICROSPHERICAL CATALYST FOR INCREASING OCTANE NUMBER OF CATALYTIC CRACKING GASOLINE AND METHOD FOR ITS PREPARATION | 2024 | 
 | RU2827818C1 | 
| MICROPSHERICAL CATALYST FOR OIL FRACTIONS CRACKING AND METHOD OF ITS MAKING | 2011 | 
 | RU2473385C1 | 
| MICROSPHERIC BIZEOLITE CATALYST FOR INCREASING OCTANE NUMBER OF PETROL OF VACUUM GAS OIL CRACKING AND METHOD OF ITS PREPARATION | 2011 | 
 | RU2473384C1 | 
| METAL-RESISTANT CRACKING CATALYST AND METHOD FOR ITS PREPARATION | 2024 | 
 | RU2832219C1 | 
| MICROSPHERICAL CATALYST FOR CRACKING OIL FRACTIONS AND METHODS OF PRODUCTION THEREOF | 2020 | 
 | RU2743935C1 | 
| MICROSPHERICAL CATALYST FOR REDUCING SULPHUR CONTENT IN CRACKED GASOLINE AND METHOD FOR PRODUCTION THEREOF | 2011 | 
 | RU2472586C1 | 
| MICRO-SPHERICAL CATALYST FOR INCREASING YIELD OF CATALYTIC CRACKING GASOLINE AND METHOD FOR ITS PREPARATION | 2021 | 
 | RU2789407C1 | 
| CATALYST FOR DEEP OIL FRACTION CRACKING AND METHOD OF ITS PREPARATION | 2008 | 
 | RU2365409C1 | 
| MICROSPHERICAL CATALYST FOR OIL FRACTIONS CRACKING | 2018 | 
 | RU2673811C1 | 
| METHOD OF PREPARING MICROSPHERICAL OIL FRACTION CRACKING CATALYST | 2005 | 
 | RU2300420C2 | 
Authors
Dates
2024-10-02—Published
2024-04-24—Filed