FIELD: organic chemistry. SUBSTANCE: synthesis of amino acids is carried out by isotope ex- change with gaseous tritium in the presence of heterogeneous palladium catalyst on barium sulfate of rhodium, or ruthenium, or platinum complex of corresponding amino acid at 160-250 C. Method ensures to increase molar radioactivity of amino acids from 4-12 Ku/mmole (by known method) to 22-112 Ku/mmole. EFFECT: enhanced molar radioactivity of products.
| Title |
Year |
Author |
Number |
| METHOD OF TRITIUM LABELED COMPOUNDS SELECTED FROM CLASSES OF AMINO ACIDS, AMINES, AMINOSUGARS, SUGARS, PURINE AND PYRIMIDINE BASES AND NUCLEOSIDES, CARBOXYLIC ACIDS, NITROGEN-CONTAINING DERIVATIVES OF TETRAHYDROTHIOPHENE |
1987 |
- Zolotarev Ju.A.
- Zajtsev D.A.
- Mjasoedov N.F.
|
SU1774613A1 |
| METHOD OF OBTAINING PEPTIDES AND GLYCOPEPTIDES MARKED BY TRITIUM |
1983 |
- Zolotarev Ju.A.
- Petrenik B.V.
- Mjasoedov N.F.
|
SU1545503A3 |
| METHOD OF SYNTHESIS OF PROLINE HIGH-LABELED WITH TRITIUM |
1986 |
- Dorokhova E.M.
- Zolotarev Ju.A.
- Kozik V.S.
- Mjasoedov N.F.
|
SU1432968A3 |
| METHOD OF SYNTHESIS OF 4-ETHYL-2,6,7-TRIOXA-1-PHOSPHOBICYCLO-[2,2,2]-OCTANE-1-OXIDE HIGHLY LABELED WITH TRITIUM OR DEUTERIUM AT ETHYL RADICAL |
1995 |
- Mjasoedov N.F.
- Shevchenko V.P.
- Faradzheva S.V.
- Nagaev I.Ju.
|
RU2108337C1 |
| TRITIUM HIGHLY MARKED COENZYME A OR ACETYL COENZYME A |
1998 |
- Shevchenko V.P.
- Mjasoedov N.F.
- Nagaev I.Ju.
|
RU2143416C1 |
| TRITIUM HIGH-LABELED DIMETHOMORPHOLINE AND METHOD OF PREPARATION THEREOF |
1998 |
- Shevchenko V.P.
- Nagaev I.Ju.
- Mjasoedov N.F.
|
RU2136672C1 |
| METHOD OF SYNTHESIS OF HEXAPEPTIDE AMINO ACID FRAGMENTS MULTIPLE-LABELED WITH TRITIUM AT α-POSITION |
1988 |
- Zolotarev Ju.A.
- Zajtsev D.A.
- Mjasoedov N.F.
|
SU1736126A3 |
| TRITIUM HIGHLY MARKED CYCLOSPORIN A |
1998 |
- Shevchenko V.P.
- Mjasoedov N.F.
- Nagaev I.Ju.
|
RU2144017C1 |
| METHOD OF PREPARING TRITIUM LABELLED ALIPHATIC α- HALOGEN ACIDS |
1995 |
- Mjasoedov N.F.
- Shevchenko V.P.
- Nezavibat'Ko V.N.
- Nagaev I.Ju.
|
RU2089531C1 |
| METHOD OF SYNTHESIS OF TETRAMETHYL-4-HYDROXY(AMINO)PIPERIDINES OR AMINODODECANOIC ACID LABELED WITH TRITIUM |
1986 |
- Shevchenko V.P.
- Potapova A.V.
|
SU1432969A3 |
