PROCESS FOR PREPARING CATALYST FOR HYDROGENATION OR BUTINDIOL-1 Russian patent published in 1995 - IPC

Abstract SU 1555941 A1

4 TO BURANEDIOL-1.4. FIELD: catalytic chemistry. SUBSTANCE: to a solution of potassium tetrachloropalladoate are added crystallohydrates of a sodium salt of tungstic acid and a potassium salt of hexaniobic acid of the formula: K7HNb6O19·12H2O in a 2 weight ration and at a tungsten and niobium to palladium atomic ration of 1-2 followed by heating the mixture to the boiling point, cooling and treating it with a reducing agent such as hydrogen, forming a palladium sol and suspending α- aluminium oxide therein, separating the resulting precipitate and drying the latter. The new catalyst has an activity of not greater than 9.7 mole/s*g Pd and a butenediol-1.4 selectivity of 98%. EFFECT: improved activity and selectivity.

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SU 1 555 941 A1

Authors

Maksimov G.M.

Zakarina N.A.

Matveev K.I.

Toktabaeva N.F.

Zakumbaeva G.D.

Kambarova T.D.

Dates

1995-01-27Published

1988-05-11Filed