FIELD: organic chemistry. SUBSTANCE: desired product has empirical formula С10H8NaNO6S2, its yield is 88% , main substance content is 83.8% . Diammonium salt of 2-nitro-4,8-disulfoacid of naphthalene is electrochemically reduced in electrolyzer. The process takes place on nickel cathode in ammonia-buffer solution having pH 7-8.5, current density being 5-15 A/dm2 at 60-70 C. Anode and cathode space of mentioned above electrolyzer are divided by cation-exchange membrane. EFFECT: improves efficiency of the method.
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Authors
Dates
1994-03-15—Published
1991-05-14—Filed