METHOD OF PREPARING SOLID CATALYST, CATALYST AND A METHOD OF SYNTHESIS OF ETHYLENE (CO)POLYMERS Russian patent published in 1995 - IPC

Abstract RU 2043150 C1

FIELD: catalytic chemistry. SUBSTANCE: prepolymer containing 40-80 g polyethylene per 1 mg-a titanium or vanadium prepared by ethylene polymerization in the presence of trialkylaluminium and product of sequence interaction of thermotreated silicon dioxide is used as catalyst. The latter has hydroxyl-groups with dibutylmagnesium or dibutylmagnesium and trialkylaluminium, fluoro- or tert.-butylchloride and compound of transient metal taken from the group involving tetraalkoxytitanium, titanium tetrachloride and vanadyl trichloride. Content in the solid product of the sequence interaction per 1 mg-a titanium or vanadium: magnesium 1-3.8 mg-a, aluminium 1.2-3.0 mg-a, chlorine 7.7-9.4 mg-a and silicon dioxide 0.5-2.5 mg-a at molar ratio of trialkylaluminium and solid product of sequence interaction at prepolymerization (as titanium or vanadium) 1.2-3. Process of (co)polymerization is carried out at 70-100 C, under total pressure 1.5 MPa, in the presence of hydrogen. EFFECT: improved method of catalyst preparing. 9 cl, 6 tbl

Similar patents RU2043150C1

Title Year Author Number
PROCESS OF PREPARING CATALYST 1990
  • Zhan Klod Andreh Belli[Fr]
  • Filipp Breh[Fr]
RU2033257C1
METHOD OF SYNTHESIS OF POLYMER OR ETHYLENE COPOLYMER 1992
  • Ehrik Dehjr[Fr]
RU2097388C1
METHOD FOR PRODUCTION OF CATALYST OF ZIEGLER-NATTE TYPE 1993
  • Alen Berardi
  • Zhoehl' Kollomb
  • Ehrik Dair
  • Dzhon Gabriel' Spekman
RU2117679C1
PRELIMINARY POLYMERIZED CATALYTIC COMPOSITION, METHOD FOR ITS PRODUCTION AND METHOD FOR PRODUCTION OF POLYOLEFFINS 1991
  • Ehrik Dehr[Fr]
  • Dzhon Gabriehl' Spikman[Gb]
RU2099358C1
SOLID COMPONENT OF CATALYST FOR (CO)POLYMERIZATION OF ETHYLENE AND OLEFINS, CATALYST FOR THIS PROCESS, AND PROCESS OF (CO)POLYMERIZATION OF ETHYLENE AND OLEFINS 1991
  • Ljuchiano Ljuchiani[It]
  • Federiko Milani[It]
  • Maddalena Pondrelli[It]
  • Italo Borgi[It]
  • Rentso Invernitstsi[It]
RU2100076C1
METHOD FOR PRODUCING CATALYST FOR POLYMERIZATION 1991
  • Monte Antonio[It]
  • Noristi Luchiano[It]
RU2050365C1
SOLID CATALYST COMPONENT, ETHYLENE (CO)POLYMERIZATION CATALYST, AND METHOD OF PREPARING ETHYLENE (CO)POLYMERS 1992
  • Federiko Milani[It]
  • Luchano Luchani[It]
  • Maddalena Pondrelli[It]
RU2089559C1
SOLID COMPONENT OF CATALYST OF (CO)POLYMERIZATION OF ETHYLENE, CATALYST, METHOD FOR PRODUCTION OF (CO)POLYMERS OF ETHYLENE 1992
  • Luchano Luchani[It]
  • Federiko Milani[It]
  • Rentso Invernitstsi[It]
  • Maddalena Pondrelii[It]
RU2073689C1
METHOD OF PREPARING SOLID ETHYLENE COPOLYMERIZATION CATALYST COMPONENT 1992
  • Luchano Luchani[It]
  • Federiko Milani[It]
  • Maddalena Pondrelli[It]
  • Rentso Invernitstsi[It]
RU2094440C1
0
SU424360A3

RU 2 043 150 C1

Authors

Klod Shamla[Fr]

Ehrik Dehr[Fr]

Dates

1995-09-10Published

1991-03-29Filed