FIELD: organic chemistry, polymers. SUBSTANCE: catalyst involves: trialkylaluminium, solid components and silane compound - substituted trifluoropropylsilane of the general formula $$$ where: R - linear or branched $$$-alkyl, $$$-cycloalkyl, free piperidinyl or piperidinyl substituted with linear or branched $$$-alkyl. Solid component - product of interaction of titanium compound containing bond titanium-halogen and electrodonor on carrier. Atomic ratio titanium : aluminium = 0.0006-0.0009, mole ratio solid component (as measured for titanium) : silane = 0.0077-0.0324. Polyolefins were synthesized at 40-90 C under atmospheric or increased pressure in the presence of catalyst indicated above. Catalyst is used in industry of plastics. EFFECT: enhanced effectiveness of catalyst. 2 cl, 3 tbl
| Title | Year | Author | Number |
|---|---|---|---|
| ELECTRON-DONATING ORGANOSILICON COMPOUNDS, CATALYST OF α-OLEFINS POLYMERIZATION | 1990 |
|
RU2039062C1 |
| COMPONENT OF CATALYST FOR POLYMERIZATION OF α-OLEFINS | 1992 |
|
RU2073688C1 |
| METHOD FOR PRODUCING CATALYST FOR POLYMERIZATION | 1991 |
|
RU2050365C1 |
| POLYOLEFIN COMPOSITION AND A METHOD OF ITS PREPARING | 1991 |
|
RU2036942C1 |
| HARD CATALYTIC COMPONENT FOR POLYMERIZATION OF OLEFINS AND A CATALYST FOR POLYMERIZATION OF OLEFINS | 0 |
|
SU1836384A3 |
| COMPONENT OF CATALYST FOR OLEFIN POLYMERIZATION | 1990 |
|
RU2032689C1 |
| METHOD OF CONTINUOUS GASE-PHASE ETHYLENE AND ITS MIXTURE POLYMERIZATION WITH α-OLEFINS AND POLYMERS | 1993 |
|
RU2116318C1 |
| CATALYST COMPONENT FOR (CO)POLYMERIZATION OF ALPHA-OLEFIN, METHOD OF ITS SYNTHESIS AND A METHOD OF POLYOLEFIN SYNTHESIS | 1990 |
|
RU2045537C1 |
| CATALYTIC SYSTEM FOR POLYMERIZATION OF OLEFINS | 1990 |
|
RU2114864C1 |
| PRELIMINARY POLYMERIZED COMPONENTS OF THE CATALYST FOR POLYMERIZATION OF OLEFINES | 2014 |
|
RU2619109C1 |
