FIELD: preparation of titanium chlorides, more particularly titanium tetrachloride. SUBSTANCE: titanium slags or ylmenite or perovskite or rutile or armalcolite or fassaite is subjected to nitration at 1000-1800 C in reducing medium of carbon particles. The resulting matrix comprising titanium nitride is chlorated with chlorinating agent at 200-500 C, to provide the resulting titanium tetrachloride. EFFECT: more efficient preparation process. 1 cl, 2 tbl
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