FIELD: metalloorganic chemistry. SUBSTANCE: product: metallocenes of the formula (I), where M1 means preferably titanium, zirconium of hafnium; R1 means residue and M2 means carbon or silicon; R4 and R5 are similar and mean hydrogen or alkyl-group; p = 1 or 2; R2 means hydrogen or alkyl-group and residues R3 are similar and mean halogen or alkyl-group and form together with alumoxane catalytic system as catalyst that can be used for polymerization of olefins. EFFECT: improved method of synthesis, enhanced effectiveness of catalyst. 6 cl
Title | Year | Author | Number |
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METHOD OF SYNDIOTACTIC POLYOLEFIN SYNTHESIS | 1992 |
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METALLOCENES WITH BENZOFUSED INDENYL DERIVATIVES, METHOD OF THEIR SYNTHESIS, METHOD OF OLEFIN POLYMER PRODUCING AND CATALYST FOR OLEFIN POLYMERIZATION | 1992 |
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METHOD OF PREPARING METALOCENES HAVING BRIDGE BONDS | 1995 |
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OLEFIN POLYMERIZATION CATALYST, METHOD OF PREPARATION THEREOF, AND METHOD OF MAKING OLEFIN POLYMER | 1993 |
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METHOD FOR PRODUCTION OF POLYOLEFINS | 1992 |
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ORGANOBORON COMPOUND, METHOD OF PREPARING THEREOF, CATALYST SYSTEM, METHOD OF PREPARING OLEFINIC POLYMER, AND POLYOLEFIN | 1997 |
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Authors
Dates
1997-06-20—Published
1992-08-06—Filed