FIELD: organic chemistry, steroids. SUBSTANCE: product: estratriens containing 14α, 17α-bridge of the general formula: (I) where: if OR3 at α-position then R1, R2 and R3 independently each of other is H, acyl-C1-C2; or R1 - benzyl or C1-C8-alkyl; if OR3 at β-position then R1, R2 and R3 independently each of other - H, C1-C12-acyl or C1-C8-alkyl. At both cases A-B - etheno- or ethano-bridge. Synthesized compounds were used for synthesis of drugs. EFFECT: improved method of synthesis. 12 cl, 1 tbl, 1 dwg
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Authors
Dates
1997-08-20—Published
1990-11-29—Filed