FIELD: chemical technology, catalytical chemistry. SUBSTANCE: invention relates to synthesis of solid components of catalyst for synthesis of ethylene (co)polymers of superhigh-molecular mass in the form of particles (mean diameter size is less 10 mcm). Reaction is carried out in the presence of H2O between: (1) liquid obtained after interaction of: (A) titanium compound containing at least one linkage Ti-OR where: R - C1 - C20-alkyl, C3 - C20-cycloalkyl or C6 - C20-aryl radical with (B) magnesium compound taken from: halides, compounds containing at least one group -OR or -OCOR bound with magnesium where: R - C1 - C20-alkyl, C3 - C20-cycloalkyl or C6 - C20-aryl; organometallic compounds; reaction products between above indicated compounds and electron-donating compounds, and (2) compound or composition exhibiting capability for halogenation and, possibly, reduction. EFFECT: improved method of synthesis. 4 cl, 4 tbl
Title | Year | Author | Number |
---|---|---|---|
COMPONENT OF CATALYST FOR OLEFIN POLYMERIZATION | 1992 |
|
RU2088594C1 |
PROPYLENE POLYMERIZATION CATALYST | 1991 |
|
RU2087485C1 |
COMPONENT OF OLEFIN-POLYMERIZATION CATALYST AND METHOD OF PREPARATION THEREOF, OLEFIN-POLYMERIZATION CATALYST | 1993 |
|
RU2124398C1 |
CATALYST FOR PROPYLENE POLYMERIZATION | 1989 |
|
RU2081883C1 |
CATALYST COMPONENT, OLEFIN POLYMERIZATION CATALYST (VARIANTS) AND METHOD OF POLYMERIZATION OF OLEFINS | 1996 |
|
RU2156260C2 |
THERMAL PLASTIC POLYOLEFIN COMPOSITION, METHOD FOR ITS PRODUCTION | 1990 |
|
RU2083611C1 |
FILM OR SHEET MATERIAL AND FILM OR SHEET ARTICLE | 1991 |
|
RU2097391C1 |
METHOD OF PREPARING THE CATALYST SOLID COMPONENT FOR ETHYLENE (CO)POLYMERIZATION, SOLID COMPONENT OF CATALYST FOR ETHYLENE (CO)POLYMERIZATION, CATALYST FOR ETHYLENE (CO)POLYMERIZATION AND A METHOD OF ETHYLENE (CO)POLYMERS SYNTHESIS | 1992 |
|
RU2081884C1 |
METHOD OF PREPARATION OF ETHYLENE POLYMERS AND ETHYLENE (CO)POLYMERIZATION CATALYST | 1991 |
|
RU2091394C1 |
COMPONENT OF CATALYST FOR POLYMERIZATION OF α-OLEFINS | 1992 |
|
RU2073688C1 |
Authors
Dates
1997-08-27—Published
1992-07-14—Filed