FIELD: production of high molecular weight compounds, particularly, production of stereoregular polydienes with the help of Zielger-Natte type catalytic systems; petrochemistry. SUBSTANCE: method is carried out by polymerization of butadiene, the process takes place in aromatic solvent with the help of catalyst. Said catalyst comprises neodium salt of alpha-substituted monocarboxylic acids, chloro-containing compound, diene and trialkyl aluminium; complex of aluminium trichloride with diphenyl oxide being used as chloro-containing compound. EFFECT: decreased plasticity of desired 1,4-cis-polybutadiene having high physical and mechanical properties. 2 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR PRODUCTION OF CIS-1,4-DIENE RUBBER | 1995 |
|
RU2099359C1 |
DIENE RUBBER PRODUCTION PROCESS | 1996 |
|
RU2109753C1 |
METHOD OF PREPARATION OF CIS-1,4,POLYBUTADIENE | 1995 |
|
RU2087489C1 |
VULCANIZABLE CIS-1,4-BUTADIENE RUBBER BASED COMPOSITION | 1998 |
|
RU2154656C2 |
METHOD OF PREPARING CIS-1,4-POLYBUTADIENE | 1996 |
|
RU2096422C1 |
METHOD OF PREPARATION OF OIL-FILLED 1,4-CIS-POLYBUTADIENE | 1994 |
|
RU2091399C1 |
METHOD FOR PREPARING CIS-1,4-DIENE RUBBER | 2003 |
|
RU2263121C2 |
METHOD FOR PRODUCTION OF BUTADIENE RUBBERS | 1997 |
|
RU2196781C2 |
METHOD OF SYNTHESIS OF CIS-1,4-POLYBUTADIENE | 1996 |
|
RU2109759C1 |
PROCESS FOR PREPARING CIS-1,4-POLYBUTADIENE AND CIS-1,4- BUTADIENE-ISOPRENE COPOLYMER | 1997 |
|
RU2127280C1 |
Authors
Dates
1997-12-20—Published
1995-02-10—Filed