FIELD: technology of high-molecular compounds. SUBSTANCE: method involves polymerization of butadiene in hydrocarbon solvent by catalyst based on rare-earth elements. Polymerization mixture is fed preliminarily in multibottom tubular reactor supplied with diffusers and confusers at the rate turbulent flow from 0.5 to 10 m/s followed by feeding a mixture in polymerizating device. Method provides synthesis of cis-1,4-polybutadiene at narrow molecular-mass distribution value, decreased plasticity and absence of gel-fraction. EFFECT: improved method of synthesis, improved quality of product, decreased catalyst consumption. 1 tbl
Title | Year | Author | Number |
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METHOD OF PREPARATION OF OIL-FILLED 1,4-CIS-POLYBUTADIENE | 1994 |
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METHOD FOR PRODUCTION OF CIS-1,4-DIENE RUBBER | 1995 |
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METHOD OF PREPARING CIS-1,4-POLYBUTADIENE | 1996 |
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METHOD FOR PRODUCTION OF 1,4-CIS-POLYBUTADIENE | 1995 |
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DIENE RUBBER PRODUCTION PROCESS | 1996 |
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METHOD OF PREPARING CIS-1,4-POLYBUTADIENE | 1998 |
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METHOD OF PREPARATION CIS-1,4-POLYBUTADIENE | 1998 |
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METHOD FOR PRODUCTION OF BUTADIENE RUBBERS | 1997 |
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PROCESS FOR PREPARING CIS-1,4-POLYBUTADIENE AND CIS-1,4- BUTADIENE-ISOPRENE COPOLYMER | 1997 |
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Authors
Dates
1998-04-27—Published
1996-03-01—Filed