FIELD: chemistry of polymers, more particularly radical polymerization initiators and cross-linking agents for polymers. SUBSTANCE: peroxide perfluoropolyethers are prepared by oxidation of tetra-fluoroethylene wit oxygen in solvent in the presence of chemical initiator at 2-15 atm using perfluoroethylene to chemical initiator ratio of higher than 35. The claimed method makes it possible to increase molecular weight of perfluoropolyethers at the same content of peroxide oxygen. EFFECT: more efficient preparation method. 12 cl, 25 ex, 3 tbl
Authors
Dates
1998-10-20—Published
1994-11-15—Filed