FIELD: manufacture of lead-free glass and glassware and decorative crystal glass products therefrom. SUBSTANCE: lead-free glass has density of at least 2.9 g/cubic cm and refraction coefficient of at least 1.545. Glass comprises (wt %): SiO2, 53-62; SrO, not higher than 3; ZrO2 not higher than 4; Na2O, 2-7; ΣSiO2+Al2O3+ZrO2, 55-65; K2O, 3-11; ΣNa2O+K2O, 8-14; CaO, not higher than 5; BaO 15-19; ZnO, 8-13; ΣSrO+BaO+ZnO, 17-32; Li2O, not higher than 2; ΣLi2O+Na2O+K2O not higher than 14; Al2O3, not higher than 3; and ΣSrO+BaO+ZnO not higher than 32. Glass comprises at least one transition metal or rare-earth metal oxide in amount not exceeding 0.1%. EFFECT: lead-free glass having density of at least 2.9 g/cubic cm and refraction coefficient of at least 1.545. 10 cl, 15 ex, 2 tbl
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Authors
Dates
1999-04-20—Published
1994-12-06—Filed