FIELD: chemistry.
SUBSTANCE: method for olefine epoxidation is invented which includes the reaction of the raw material containing olefine, oxygen and organic halogenide, in presence of the catalyst containing silver and rhenium precipitated on the carrier where the catalyst contains rhenium at 1.5 mol/kg of the catalyst mass, at maximum, and 0.0015 mmol/m3 of the carrier surface, at maximum, and where the reaction temperature is increased so as to partially reduce the effect of catalyst loss, and the halogenide is presented in relative Q amount which is maintained constant and where the relative amount of Q is the ratio of the effective molar amount of the active halogen compound in the raw material, to the effective molar amount of hydrocarbon, in the raw material. The invention also implies the method for producing the 1,2-diol, the simple ether of the 1,2-diol and/or alkanolamine and the catalyst to be applied in the said method.
EFFECT: stability of catalyst activity is increased.
22 cl, 8 tbl, 3 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF IMPROVING SELECTIVITY OF CATALYST AND A OLEFIN EPOXIDATION PROCESS | 2003 |
|
RU2314156C2 |
METHOD AND SYSTEM FOR OLEFIN EPOXYDATION | 2002 |
|
RU2296126C2 |
METHOD AND SYSTEMS FOR EPOXIDATION OF OLEFIN | 2002 |
|
RU2294327C2 |
METHOD FOR IMPROVING EFFICIENCY OF CATALYST FOR PRODUCING ETHYLENE OXIDE | 2011 |
|
RU2588118C2 |
METHOD OF OBTAINING OLEFIN OXIDE | 2004 |
|
RU2345073C2 |
METHOD FOR IMPROVING SELECTIVITY OF EO CATALYST | 2011 |
|
RU2583786C2 |
CATALYST AND METHOD OF ITS APPLICATION | 2003 |
|
RU2342190C2 |
REACTOR SYSTEM, ABSORBENT AND METHOD OF CONDUCTING REACTION IN FED MATERIAL | 2008 |
|
RU2474470C2 |
METHOD OF INCREASING SELECTIVITY OF EPOXIDATION CATALYST | 2012 |
|
RU2606504C2 |
CATALYST COMPOSITION INCLUDING SILVER, METHOD FOR OBTAINING SAME, AND APPLICATION OF CATALYST COMPOSITION IN ETHYLENE EPOXIDATION | 2004 |
|
RU2333034C2 |
Authors
Dates
2008-07-10—Published
2004-03-30—Filed