FIELD: organic chemistry, steroids, pharmacy. SUBSTANCE: invention relates to derivatives of prednisolone of the general formulas (I) 
, (Ia) 
and (Ib) 
showing effectiveness for treatment and prophylaxis of skin and upper respiratory way diseases. Compounds of the formula (I) are synthesized by interaction of 16-hydroxyprednisolone with cyclohexane aldehyde. EFFECT: improved method of synthesis, enhanced effectiveness of treatment and prophylaxis. 9 cl, 1 tbl, 17 ex
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