FIELD: fine organic synthesis, more particularly original semiproducts for preparing biological active agents for medicine and agriculture, and addition agents for oils. SUBSTANCE: method comprises reacting toluene solution of C60 fullerene with excessive amount of ether solution of α,ω-dimagnesium bromide, in the presence of catalyst under normal conditions for 8-24 hours and subsequently treating reaction mixture with 5% aqueous hydrochloric acid. Combined yield of final products is 56-92%. EFFECT: more efficient preparation method. 1 ex, 1 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD FOR JOINT PREPARATION OF MONO(CYCLOALKYL)DIMAGNESIUMBROMIDEFULLERENES(60) AND BIS(CYCLOALKYL)TETRAMAGNESIUMBROMID- EFULLERENES(60) | 1998 |
|
RU2136688C1 |
METHOD OF PREPARING 1-(N-PROPYL)-2-HYDRO[6] FULLERENES | 1998 |
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RU2135446C1 |
METHOD OF SYNTHESIS OF 1-ARYL-(ALKYL)-2-HYDRO[60]-FULLERENES | 1998 |
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METHOD OF SYNTHESIS OF 1-ETHYL-MAGNESIUM HALIDE (60)-FULLERENES | 1998 |
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RU2135505C1 |
METHOD OF SYNTHESIS OF 1-ARYL(ALKYL)-2-MAGNESIUM HALOGEN(60)- -FULLERENES | 1998 |
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RU2135506C1 |
METHOD OF PREPARING 1-(n-PROPYL)-2-MAGNESIUM HALOGEN (60) FULLERENES | 1998 |
|
RU2135504C1 |
METHOD OF PREPARING N-BUTYL SUBSTITUTED C. FULLERENES | 1998 |
|
RU2134255C1 |
METHOD OF SYNTHESIS OF ETHYL-CONTAINING C-FULLERENES | 1998 |
|
RU2133727C1 |
METHOD OF PREPARING 1-BUTYL-2-MAGNESIUMBUTYLFULLERENES(60) | 1998 |
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RU2136687C1 |
METHOD OF SYNTHESIS OF ETHYLATED FULLERENES | 1997 |
|
RU2119449C1 |
Authors
Dates
1999-09-10—Published
1998-04-29—Filed