FIELD: organic synthesis. SUBSTANCE: toluene solution of fullerene(60) interacts with excess of ether solution of α,ω- dimagnesium bromide in presence of zirconacene dichloride as catalyst for 10-20 hr under argon atmosphere and normal conditions to give products with yields 62-88%. EFFECT: extended synthetic possibilities. 1 tbl, 8 ex
Title | Year | Author | Number |
---|---|---|---|
METHOD OF COMBINED PREPARATION OF MONO[CYCLOALKYL]DIHYDRO[60] FULLERENES AND BIS[CYCLOALKYL]TETRAHYDRO [60] FULLERENES | 1998 |
|
RU2136647C1 |
METHOD OF PREPARING 1-BUTYL-2-MAGNESIUMBUTYLFULLERENES(60) | 1998 |
|
RU2136687C1 |
METHOD OF SYNTHESIS OF 1-ARYL(ALKYL)-2-MAGNESIUM HALOGEN(60)- -FULLERENES | 1998 |
|
RU2135506C1 |
METHOD OF PREPARING 1-(n-PROPYL)-2-MAGNESIUM HALOGEN (60) FULLERENES | 1998 |
|
RU2135504C1 |
METHOD OF SYNTHESIS OF 1-ETHYL-MAGNESIUM HALIDE (60)-FULLERENES | 1998 |
|
RU2135505C1 |
METHOD OF SYNTHESIS OF ETHYL-CONTAINING C-FULLERENES | 1998 |
|
RU2133727C1 |
METHOD OF SYNTHESIS OF ETHYLATED FULLERENES | 1997 |
|
RU2119449C1 |
METHOD OF SYNTHESIS OF 1-ARYL-(ALKYL)-2-HYDRO[60]-FULLERENES | 1998 |
|
RU2135447C1 |
METHOD OF PREPARING 1-(N-PROPYL)-2-HYDRO[6] FULLERENES | 1998 |
|
RU2135446C1 |
METHOD OF PREPARING N-BUTYL SUBSTITUTED C. FULLERENES | 1998 |
|
RU2134255C1 |
Authors
Dates
1999-09-10—Published
1998-04-29—Filed