FIELD: organic chemistry, more particularly, chemical and pharmaceutical industries. SUBSTANCE: described is method of preparing polyfluoroalkylmethyl ketone of general formula I: RFC(O)CH3 wherein by hydrolysis of fluorine-containing esters in the presence of sulfuric acid on heating. Original products include polyfluorinated esters of enol beta-diketones, and process is carried out at temperature of 100-200 C in the presence of 94-98% sulfuric acid. EFFECT: more efficient method of preparing polyfluoroalkylmethyl ketones with high yield. 8 ex
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Authors
Dates
1999-12-27—Published
1998-07-06—Filed