FIELD: polymerization catalysts. SUBSTANCE: at least one olefin is brought into contact with catalytic system containing solid catalytic complex based on magnesium, transition metal, and halogen; and organometallic compound with Ia, IIa, IIb, IIIa, and IVa group metals. Solid catalytic complex is prepared by interaction of at least one magnesium compound with at least one IVb or Vb group transition metal to form liquid complex, which is then precipitated in solid form by agency of halogen-containing organoaluminum compound. Solid complex is separated and treated with halogen-containing organoaluminum compound having general formula AlRnX3-n. EFFECT: increased apparent density of polyolefins. 19 cl, 4 ex
Authors
Dates
1999-12-27—Published
1995-09-21—Filed