FIELD: chemical technology. SUBSTANCE: invention relates to production of hexafluoropropylene used as comonomer in production of fluoroplastics and fluorinated rubber and as raw for synthesis of some fluoroorganic substances. Process is carried out at 0-50 C by bubbling of gaseous hexafluoropropylene through oleum or by mixing liquid hexafluoropropylene with oleum under autogenic pressure for 10-30 min. Oleum is taken in the amount 1 mole (by sulfur trioxide), not less, per 1 mole of trifluorochloroethylene in hexafluoropropylene to be purified and containing 2-30 wt.% of sulfur trioxide. EFFECT: production of trifluorochloroethylene-free hexafluoropropylene. 1 cl, 3 ex
| Title | Year | Author | Number | 
|---|---|---|---|
| METHOD FOR COMPLEX ISOLATION OF DIFLUOROCHLOROMETHANE AND HEXAFLUOROPROPYLENE | 2002 | 
 | RU2211209C1 | 
| 1,1-DIFLUOROETHANE PRODUCTION PROCESS | 1997 | 
 | RU2150452C1 | 
| METHOD OF SYNTHESIS OF 1,1,1,2,3,3,3-HEPTAFLUOROPROPANE | 1998 | 
 | RU2165918C2 | 
| METHOD OF SYNTHESIS OF PERFLUORODIACYL PEROXIDE | 2001 | 
 | RU2203273C1 | 
| 0 |  | SU327148A1 | |
| METHOD FOR PREPARING TRIFLUOROCHLOROETHYLENE TERPOLYMER | 2001 | 
 | RU2208018C2 | 
| OCTAFLUOROCYCLOBUTANE AND HEXAFLUOROPROPYLENE PRODUCTION PROCESS | 2001 | 
 | RU2186052C1 | 
| METHOD OF PURIFYING 1,1,1-FLUORODICHLOROETHANE | 1998 | 
 | RU2157362C2 | 
| SULFUR HEXAFLUORIDE PRODUCTION REACTOR | 1998 | 
 | RU2154018C2 | 
| PROCESS FOR INTEGRATED PRODUCTION OF FLUOROCARBONS | 2001 | 
 | RU2188814C1 | 
Authors
Dates
2000-06-10—Published
1997-01-10—Filed