FIELD: chemistry of polymers, more particularly preparation of modified low molecular (co)polymers based on diene monomers, more specifically maleic anhydride-low molecular (co)polymer adducts. SUBSTANCE: in method of preparing maleic anhydride-low molecular (co)polymer adducts based on diene monomers or diene monomers or copolymers of diene monomers and styrene in inert gas atmosphere at 190-250 C, gel formation inhibitor includes product of reaction of maleinized (co)polymer based on diene monomers or diene monomer-styrene copolymer having molecular weight of 600- 2000 and comprising 5-25 wt % of bonded maleic anhydride with paraaminodiphenyl amine in bonded maleic anhydride to para-aminodiphenyl amine molar ratio of 1:0.8-1.0, respectively in amount of 0.01-0.20 g-mole of bonded para-aminophenyl amine per 1000 g of low molecular (co)polymer used for preparing adduct. Method makes it possible to reduce viscosity of maleic anhydride-low molecular (co)polymer adducts due to suppressing gel formation during manufacture thereof, thus improving technological efficiency of the resulting adducts during use thereof. EFFECT: more efficient preparation method. 8 ex, 2 tbl
Title | Year | Author | Number |
---|---|---|---|
METHOD OF PREPARING EMULSION POLYMERIZATION RUBBERS | 1996 |
|
RU2130035C1 |
METHOD OF PREPARING POLYMERIC AMINE ANTIOXIDANT | 1996 |
|
RU2130033C1 |
METHOD OF STABILIZING EMULSION-POLYMERIZATION RUBBERS | 1996 |
|
RU2123015C1 |
PROCESS FOR PREPARING LOW-MOLECULAR POLYMERS | 1995 |
|
RU2082718C1 |
METHOD OF STABILIZATION OF EMULSION POLYMERIZATION RUBBERS | 1996 |
|
RU2130031C1 |
METHOD OF PREPARING ANTIOXIDANT FOR EMULSION POLYMERIZATION RUBBERS | 1996 |
|
RU2130013C1 |
METHOD OF PRODUCING ADDUCTS OF MALEIC ANHYDRIDE WITH LOW-MOLECULAR (CO) | 2009 |
|
RU2424250C1 |
METHOD FOR PRODUCING BUTADIENE POLYMERS AND BUTADIENE/STYRENE COPOLYMERS | 1995 |
|
RU2074197C1 |
METHOD OF PREPARING DIENE COPOLYMERS (VARIANTS) | 1996 |
|
RU2124529C1 |
METHOD FOR PURIFICATION OF POLYMER AGAINST RESIDUE OF HYDROGENATION CATALYST CONTAINING NICKEL CATALYST | 1992 |
|
RU2043996C1 |
Authors
Dates
2000-07-27—Published
1996-12-25—Filed