FIELD: petrochemical processes. SUBSTANCE: raw material containing hydrocarbons and oxygen-containing gas is brought into contact with catalyst at elevated temperature, said catalyst having porous monolith structure and including catalytically active metal deposited on zirconium oxide-based carrier. When starting or stopping reactor, catalyst is subjected to heat shock within temperature range at least 500 C with rate at least 50 C/min. EFFECT: increased selectivity with respect to carbon monoxide and hydrogen and increased catalytic activity and resistance to heat shock. 16 cl, 1 tbl, 4 ex
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