FIELD: chemical industry. SUBSTANCE: described is method of preparing polyolefin which comprises polymerization of alpha-olefin in the presence of catalyst system containing cocatalyst and catalyst. Also described is catalyst system in which azametallocene catalyst has at least one ligand containing pyrrolyl group bonded with transition metal which group contains nitrogen-containing 5-membered resonance ring. EFFECT: increased catalytic activity of nitrogen-containing polymerization catalysts at high temperatures to prepare polymers with narrow molecular weight destribution. 24 cl, 26 ex
Title |
Year |
Author |
Number |
CATALYST OF OLEFIN POLYMERIZATION AS AZABOROLINYL METAL COMPLEXES AND METHOD OF SYNTHESIS OF POLY-α-OLEFIN (VARIANTS) |
1996 |
- Krishnehmurti Rehmesh
- Nehjgi Sandor
- Ehzerton Brehdli P.
|
RU2167879C2 |
CATALYTICAL SYSTEM, METHOD OF ETHYLENE POLYMERIZATION AND METHOD OF POLYMERIZATION OF LINEAR AND BRANCHED α-OLEFINS |
1996 |
- Koukehmehn Mehri
- Kribbs Leonard V.
- Krishnehmurti Rehmesh
- Nehjgi Sandor
- Tajrell Dzhon Eh.
|
RU2169735C2 |
CATALYST COMPOSITION USED FOR OLEFIN POLYMERIZATION |
1993 |
- Kristin Zhaklin Shabran
- Jan Rejmond Littl
- Dzhon Pol Maknelli
|
RU2126424C1 |
CATALYST COMPOSITION USED FOR POLYMERIZATION OF OLEFINS |
1993 |
- Jan Rejmond Littl
- Dzhon Pol Maknelli
|
RU2165435C2 |
CATALYTIC COMPOSITION AND OLEFIN POLYMERIZATION PROCESS |
1995 |
- Jokhannus Antonius Marija Van Bek
- Gerardus Khenrikus Jozefus Van Doremale
- Gerardus Jokhannes Marija Grjuter
- Khenrikus Jokhannes Arts
- Gejllaume Khermanus Marija Rene Ehggels
|
RU2135522C1 |
PREPOLYMERIZED CATALYST, CATALYST SYSTEM (VARIANTS), METHOD OF PREPARATION OF POLYOLEFINS (VARIANTS), POLYMERIC COMPOSITION, AND MOLDED PRODUCT |
1992 |
- Tetsunori Sinozaki[Jp]
- Matoru Kioka[Jp]
|
RU2091391C1 |
POLYMER COMPOSITION |
1992 |
- Tetsunori Sinozaki[Jp]
- Mamoru Kioka[Jp]
|
RU2092501C1 |
METALLOCENES, METHOD OF PREPARING THEREOF, CATALYST SYSTEM, METHOD OF PREPARING POLYOLEFINS, AND MOLDED POLYMERIC PRODUCT |
1994 |
- Frank Kjuber
- Mikhael' Aulbakh
- Bernd Bakhmann
- Val'Ter Shpalek
- Andreas Vinter
|
RU2147587C1 |
CATALYST COMPOSITION, METALLOCENE COMPLEX AND METHOD OF POLYMERIZATION OF OLEFINS |
1994 |
|
RU2156253C2 |
METHOD OF PURIFICATION OF α-OLEFINS FOR POLYMERIZATION AND METHOD OF SYNTHESIS OF POLY-α-OLEFINS |
1995 |
- Ito Josinao
- Jasuda Kazuo
- Simonisi Sougo
|
RU2152421C1 |