FIELD: processing of natural clay materials more particularly preparation of granular synthetic zeolites as adsorbents and catalysts. SUBSTANCE: natural clay material is thermally activated, mixed with alumosilicon hydrogel and amorphous silica is added to reaction mixture, mixture is granulated, dried and hydrothermal crystallization is carried out in alkaline solution which is sodium hydroxide having concentration of 40-60 g/l in admixture with lithium hydroxide and in the presence of silicate- or aluminate- ion depending on SSS molar ratio. Crystallization is carried out at clay material to lithium hydroxide molar ratio of 100:0.1-0.5 at 85-100 C for 20-36 h. Invention makes it possible to shorten crystallization time. EFFECT: more efficient preparation method. 2 ex, 3 tbl
Title | Year | Author | Number |
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METHOD FOR PRODUCTION OF GRANULATED ZEOLITE OF FAUJASITE TYPE BASED ON NATURAL CLAY MATERIALS | 1992 |
|
RU2033966C1 |
METHOD FOR PRODUCTION OF GRANULATED ZEOLITE OF A TYPE BASED ON NATURAL CLAY MATERIAL | 1992 |
|
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METHOD OF PRODUCTION OF SYNTHETIC GRANULATED FAUJASITE | 1999 |
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METHOD OF PRODUCTION OF SYNTHETIC ZEOLITE, TYPE A | 1999 |
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METHOD OF SYNTHETIC FAUJASITE PRODUCING | 1997 |
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CARBON-MINERAL GRANULATED ZEOLITE-BASED ADSORBENT | 1997 |
|
RU2124942C1 |
ZEOLITE X PRODUCTION METHOD | 1998 |
|
RU2142412C1 |
METHOD OF PREPARING TYPE A ZEOLITE | 1998 |
|
RU2141451C1 |
METHOD OF PREPARING GRANULATED SYNTHETIC ZEOLITES | 2005 |
|
RU2283279C1 |
METHOD OF PREPARING HIGH PHASE-PURITY GRANULATED A-TYPE ZEOLITE | 2005 |
|
RU2283281C1 |
Authors
Dates
2001-10-20—Published
1999-05-11—Filed