FIELD: organic chemistry, agriculture, herbicides. SUBSTANCE: invention describes an agent used for protection of cultured plants from phytotoxic adverse effect of herbicides from the group of sulfonylureas, imazetapir, phenoxyprop- ethyl, 2,6-bis-[(4,6-dimethoxypyrimidin-2-yl)oxy]benzoic acid sodium salt comprising compound of the formula (I) where R1 means hydrogen atom, unsubstituted C1-C12-alkyl or that substituted with one or more similar or different radicals taken among the group: halogen atom, hydroxy-group, unsubstituted phenyl or phenyl substituted with halogen atom, radical of the group Za- Ra; C2- C8-alkenyl; C3- C8-cycloalkyl; C1- C8-alkoxy-group; C1- C8-alkylthio-group; phenyl substituted with one or more similar or different radicals taken among the group: C1- C4- alkoxy-group, halogen atom; furanyl, thienyl; R2- means hydrogen atom; R1 and R2 in common with the group CO-N- form 5- membered saturated heterocyclic ring; R3 means halogen atom, radical of the formula -Zb- Rb; R4- means hydrogen atom; R5- means halogen atom, nitro-, hydroxy-group, radical of the formula -Zc- Rc; Ra means C1- C8-alkyl, unsubstituted phenyl or phenyl substituted with halogen atom; Rb, Rc mean independently each of other unsubstituted C1- C8-alkyl or that substituted with halogen atom; Za means groups: -O-, -CO-O-, -NH; Zb,Zc mean independently each of other groups: -O-, -S-, -CO-O-, -NH- being a bond indicated from the right is a bond with a residue Ra,Rb or Rc; n = 0, 1, 2; m = 0, 1, 2, 3, or alkaline metals salts. Invention describes also novel N-acylsulfonamides of the general formula (I) and their alkaline metals salts used in the agent. N- acylsulfonamides decrease and eliminate adverse phytotoxic effects of herbicides on cultured plants significantly. EFFECT: valuable protective effects of agents. 7 cl, 2 tbl
Authors
Dates
2002-05-20—Published
1997-05-06—Filed