FIELD: fluoroorganic chemistry, chemical technology. SUBSTANCE: compounds synthesized in reaction of hydrodefluorination are used as intermediate substances. Hydrodefluorination reaction of CF3-group is carried out with aluminium chloride and cyclic-C5- C6 or aliphatic-C5- C12 hydrocarbon in medium of chloroorganic solvent at heating from 30 to 80 C. Method provides the selective hydrodefluorination of CF3-group in polyfluoroalkylbenzenes using low-priced and available raw. EFFECT: improved method of hydrodefluorination, decreased cost. 1 tbl, 9 ex
| Title | Year | Author | Number |
|---|---|---|---|
| METHOD OF SYNTHESIS OF PERFLUORINATED ETHERS WITH TERMINAL FUNCTIONAL GROUPS | 2000 |
|
RU2179548C2 |
| METHOD OF PREPARING POLYFLUOROAROMATIC COMPOUNDS | 1999 |
|
RU2164508C1 |
| METHOD OF PREPARING POLYFLUORINATED ALKOXYPROPIONYL FLUORIDES | 2002 |
|
RU2230057C1 |
| METHOD OF SYNTHESIS OF POLYFLUOROALKANES | 2001 |
|
RU2189966C1 |
| METHOD FOR PRODUCING TRIMETHYL(TRIFLUOROMETHYL)SILANE | 2014 |
|
RU2550139C1 |
| METHOD OF OBTAINING MONO- AND DIHYDROXYPOLYFLUOROBENZENES | 2013 |
|
RU2536872C1 |
| METHOD OF PROCESSING ORGANOCHLORINE WASTES VIA LIQUID-PHASE CATALYTIC HYDRODECHLORINATION | 2010 |
|
RU2458030C1 |
| METHOD OF SYNTHESIS OF DERIVATIVE OF DEOXYURIDINE | 1998 |
|
RU2204564C2 |
| METHOD OF PRODUCING BRANCHED HYDROCARBON COMPONENT | 2006 |
|
RU2407778C2 |
| METHOD OF SYNTHESIS OF ADDUCTS OF FLUORO-CONTAINING HYDROCARBONS AND OLEFINS | 1997 |
|
RU2181114C2 |
