METHOD OF OBTAINING MONO- AND DIHYDROXYPOLYFLUOROBENZENES Russian patent published in 2014 - IPC C07C39/27 C07C39/24 C07C37/01 

Abstract RU 2536872 C1

FIELD: chemistry.

SUBSTANCE: method includes obtaining trimethylsilyl ether or bis-trimethylsilyl ether from respective fluorine-containing mono- or bi-basic aromatic acid by its interaction with trimethylchlorosilane, its conversion into respective zinc derivative resulting from reaction with zinc salt or zinc oxide in polar aprotic solvent, such as dimethylformamide, dimethylacetamide, acetonitrile, N-methylpyrollidone, oxidation of obtained zinc derivative in the same solvent with peroxy compoubd in presence of salts of monovalent copper CuX, where X=Cl, Br, I, and further processing with concentrated hydrochloric acid, after which target mono- or dihtdroxypolyfluorobenzene is separated by known methods.

EFFECT: method makes it possible to obtain target compounds with outputs.

5 cl, 1 tbl, 4 ex

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RU 2 536 872 C1

Authors

Igumnov Sergej Mikhajlovich

Bojko Vladimir Ehduardovich

Dates

2014-12-27Published

2013-11-12Filed