FIELD: petrochemical processes. SUBSTANCE: catalyst used in production of hydrogen/carbon monoxide mixture through catalytic conversion of hydrocarbons in presence of oxygen-containing gases and/or water steam is a complex composite containing mixed oxides with perofskite and fluorite structure and transition and/or precious metals, which additionally contains components with low thermal expansion coefficient. Invention describes catalytic conversion of mixture containing hydrocarbon and/or hydrocarbon mixture and air or carbon dioxide, or water steam, or their mixture, and optionally sulfur-containing compounds. EFFECT: increased heat resistance and resistance against carbonization and poisoning with sulfur-containing compounds. 6 cl, 4 tbl, 27 ex
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